Structure of (C3H5NH3)2H2P2O7·H2O
Identifieur interne : 001A86 ( Main/Exploration ); précédent : 001A85; suivant : 001A87Structure of (C3H5NH3)2H2P2O7·H2O
Auteurs : E. H. Soumhi [Tunisie] ; I. Saadoune [Tunisie] ; A. Driss [Tunisie] ; T. Jouini [Tunisie]Source :
- European Journal of Solid State and Inorganic Chemistry [ 0992-4361 ] ; 1998.
English descriptors
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Abstract
Abstract: The bis(cyclopropylammonium)dihydrogenodiphosphate monohydrate is a new diphosphate associated with the organic molecule C3H5NH2. We report the chemical preparation and the crystal structure of this organic cation diphosphate. (C3H5NH3)2H2P2O7.H2O is orthorhombic (S.G. : P212121), with Z = 4 and the following unit-cell parameters : a = 4.828(1) Å, b = 11.011(1) Å, c = 25.645(2) Å. The P2O7 groups and H2O water molecules form a succession of bidimensional layers perpendicular to the c axis. The organic cations ensure the three-dimensional cohesion by NH-O hydrogen bonds.
Url:
DOI: 10.1016/S0992-4361(99)80010-1
Affiliations:
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We report the chemical preparation and the crystal structure of this organic cation diphosphate. (C3H5NH3)2H2P2O7.H2O is orthorhombic (S.G. : P212121), with Z = 4 and the following unit-cell parameters : a = 4.828(1) Å, b = 11.011(1) Å, c = 25.645(2) Å. The P2O7 groups and H2O water molecules form a succession of bidimensional layers perpendicular to the c axis. The organic cations ensure the three-dimensional cohesion by NH-O hydrogen bonds.</div></front></TEI><affiliations><list><country><li>Tunisie</li></country><region><li>Gouvernorat de Tunis</li></region><settlement><li>Tunis</li></settlement></list><tree><country name="Tunisie"><noRegion><name sortKey="Soumhi, E H" sort="Soumhi, E H" uniqKey="Soumhi E" first="E. H." last="Soumhi">E. H. Soumhi</name></noRegion><name sortKey="Driss, A" sort="Driss, A" uniqKey="Driss A" first="A." last="Driss">A. Driss</name><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">T. 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